Fubridazole - CAS 3878-19-1
Catalog number: 3878-19-1
Category: Inhibitor
Not Intended for Therapeutic Use. For research use only.
Molecular Formula:
C11H8N2O
Molecular Weight:
184.19
COA:
Inquire
Targets:
Others
Description:
Fuberidazole is a benzimidazole based fungicide used in cereal seed dressing and fungicidal non-mercurial seed dressing with special action against fusarium.
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Purity:
≥98%
Appearance:
Off-White to Pale Beige Solid
Synonyms:
2-(furan-2-yl)-1H-benzimidazole; BAY 33172;
Solubility:
Soluble in DMSO
Storage:
Store at -20 °C
MSDS:
Inquire
Application:
A fungicidal seed treatment of barley.
Quality Standard:
Enterprise standard
Shelf Life:
As supplied, 2 years from the QC date provided on the Certificate of Analysis, when stored properly.
Quantity:
Milligrams-Grams
Melting Point:
>280ºC (dec.)
InChIKey:
UYJUZNLFJAWNEZ-UHFFFAOYSA-N
InChI:
1S/C11H8N2O/c1-2-5-9-8(4-1)12-11(13-9)10-6-3-7-14-10/h1-7H,(H,12,13)
Canonical SMILES:
C1=CC=C2C(=C1)NC(=N2)C3=CC=CO3
Current Developer:
Bayer
1.Multiresidue analysis of pesticides in urine of healthy adult companion dogs.
Forster GM1, Brown DG, Dooley GP, Page RL, Ryan EP. Environ Sci Technol. 2014 Dec 16;48(24):14677-85. doi: 10.1021/es503764s. Epub 2014 Nov 26.
The objective of this study was to determine the background exposures to pesticides as detected in urine from 21 healthy companion dogs in Northern Colorado. A panel of 301 pesticides was used to screen urine samples collected from dogs using an established ultraperformance liquid chromatography-mass spectrometry (UPLC-MS/MS) platform. Canine food intakes were controlled for one month on diets that were also screened for pesticide contents. Fifteen distinct pesticides were detected in urine. The most frequently detected compounds in canine urine samples collected over a 1 month period were atrazine, fuberidazole, imidacloprid, terbumeton, and clopyralid. Fuberidazole was the only pesticide detected in both the diets and urine. Companion dogs develop many similar chronic diseases as humans and represent a relevant model for biomonitoring combinations of environmental pesticide exposures, as well as for evaluating the potential relationships between environmental exposures and disease risk.
2.Salting-out assisted liquid-liquid extraction with the aid of experimental design for determination of benzimidazole fungicides in high salinity samples by high-performance liquid chromatography.
Wen Y1, Li J, Yang F, Zhang W, Li W, Liao C, Chen L. Talanta. 2013 Mar 15;106:119-26. doi: 10.1016/j.talanta.2012.12.011. Epub 2012 Dec 14.
A novel method for the simultaneous separation and determination of four benzimidazole fungicides (i.e., carbendazim, fuberidazole, thiophanate-methyl and thiophanate) in high salinity samples was developed by using salting-out assisted liquid-liquid extraction (SALLE) via water-miscible acetonitrile as the extractant coupled with high-performance liquid chromatography. Box-Behnken design and response surface were employed to assist the optimization of SALLE conditions, including volume of salting-out solvent, the pH of sample solution and salting-out solvent as variable factors. The optimal salting-out parameters were obtained as follows: 2 mL of acetonitrile was added to 2 mL of sample solution with pH=4 and then 2 mL salting-out solvent containing 5 mol L(-1) sodium chloride at a pH of 7 was added to the solution for extraction. This procedure afforded a convenient and cost-saving operation with good cleanup ability for the benzimidazole fungicides, such as good linear relationships (R>0.
3.Determination of five pesticides in juice, fruit and vegetable samples by means of liquid chromatography combined with multivariate curve resolution.
Boeris V1, Arancibia JA1, Olivieri AC2. Anal Chim Acta. 2014 Mar 3;814:23-30. doi: 10.1016/j.aca.2014.01.034. Epub 2014 Jan 18.
The aim of this work was to quantify five commonly used pesticides (propoxur, carbaryl, carbendazim, thiabendazole and fuberidazole) in real samples as: tomato, orange juice, grapefruit juice, lemon and tangerine. The method used for the determination of these analytes in the complex matrices was high-performance liquid chromatography with diode array detection. In order to work under isocratic conditions and to complete each run in less than 10 min, the analysis was carried out applying multivariate curve resolution coupled to alternating least-squares (MCR-ALS). The flexibility of this applied multivariate model allowed the prediction of the concentrations of the five analytes in complex samples including strongly coeluting analytes, elution time shifts, band shape changes and presence of uncalibrated interferents. The obtained limits of detection (in μg L(-1)) using the proposed methodology were 2.3 (carbendazim), 0.90 (thiabendazole), 12 (propoxur), 0.
4.Determination of benzimidazolic fungicides in fruits and vegetables by supramolecular solvent-based microextraction/liquid chromatography/fluorescence detection.
Moral A1, Sicilia MD, Rubio S. Anal Chim Acta. 2009 Sep 21;650(2):207-13. doi: 10.1016/j.aca.2009.07.056. Epub 2009 Jul 29.
A supramolecular solvent consisting of vesicles, made up of equimolecular amounts of decanoic acid (DeA) and tetrabutylammonium decanoate (Bu4NDe), dispersed in a continuous aqueous phase, is proposed for the extraction of benzimidazolic fungicides (BFs) from fruits and vegetables. Carbendazim (CB), thiabendazole (TB) and fuberidazole (FB) were extracted in a single step and no clean-up or concentration of extracts was needed. The high extraction efficiency obtained for BFs was a result of the different types of interactions provided by the supramolecular solvent (e.g. hydrophobic and hydrogen bonds) and the high number of solubilisation sites it contains. Besides simple and efficient, the proposed extraction approach was rapid, low-cost, environment friendly and it was implemented using conventional lab equipments. The target analytes were determined in the supramolecular extract by LC/fluorescence detection. They were separated in a Kromasil C18 (5 microm, 150 mm x 4.
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Chemical Structure

CAS 3878-19-1 Fubridazole

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