Deoxylapachol - CAS 3568-90-9
Catalog number: 3568-90-9
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Molecular Formula:
C15H14O2
Molecular Weight:
226.3
COA:
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Chemical Family:
Quinones
Description:
Deoxylapachol isolated from the leaves of Catalpa ovata G. Don.
Purity:
> 95%
Appearance:
Yellow oil
Synonyms:
2-(3-methylbut-2-enyl)naphthalene-1,4-dione
MSDS:
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Quality Standard:
Enterprise Standard
Quantity:
Milligrams-Grams
1.Occupational allergic contact dermatitis caused by wood dusts.
Estlander T;Jolanki R;Alanko K;Kanerva L Contact Dermatitis. 2001 Apr;44(4):213-7.
Exposure to wood dusts may cause various skin and mucosal symptoms. Allergic dermatoses, caused by wood dusts, diagnosed at the Finnish Institute of Occupational Health during 1976-1999 are reported here. 16 had allergic contact dermatitis and, 2 had contact urticaria. 9 men (3 cabinet makers, 3 joiners, 1 carpenter, 1 knifemaker and 1 machinist) were mainly exposed to tropical hardwoods. 1 man had dermatitis caused by western red cedar. 5 patients, 3 men and 2 women, were exposed to Finnish pine or spruce dusts, and 1 man to aspen. 7 also had rhinitis, 4 asthma or dyspnoea and 3 conjunctivitis. On patch testing, 10 men reacted to 9 different wood dusts, including teak (5), palisander (3), jacaranda (2), mahogany (2), walnut (2) and obeche (1). Reactions to wood allergens, including lapachol (2), deoxylapachol (1), (R)-3,4-dimethoxydahlbergione (2), 2,6-dimethoxy-1,4-benzoquinone (1), mansonone A (2) and salicyl alcohol (1), were noted in 4 cases. All but 1 of 5 patients exposed to pine or spruce dusts reacted to the sawdusts, all 5 to colophonium, 3 to abietic acid, 2 to tall oil resin, 3 to wood tar mix and 4 to other wood gum resins. Of the 2 CU patients, 1 was prick and RAST positive to obeche, 1 reacted with urticarial dermatitis to punah wood dust on chamber exposure.
2.Chemical markers of occupational exposure to teak wood dust.
Carrieri M;Bartolucci GB;Lee T;Barbero A;Harper M Ann Occup Hyg. 2014 Jun;58(5):566-78. doi: 10.1093/annhyg/meu016. Epub 2014 Mar 26.
A novel high-performance liquid chromatographic/ultraviolet method was developed to detect lapachol (LP) and deoxylapachol (DLP) in wood dust as chemical markers of teak wood (a suspected human carcinogen). The specificity of this analysis was determined by noting the absence of LP and DLP in 12 other specimens of different woods belonging to the angiosperm family. The consistency was examined by analyzing teak from three different sources, where the percentages (wt/wt) of the chemicals ranged from 0.006 to 0.261 for LP and from 0.038 to 0.497 for DLP, respectively. Although the LP and DLP components of teak varied according to source, a very high correlation coefficient (r (2) > 0.98 always) was found between the content of the two markers in the bulk specimens and in bulk dust derived from them. The method was then applied to teak dust collected on polyvinylchloride filters from aerosol in an exposure chamber in the range of mass loadings between 0.03 and 3.65 mg, which corresponds to a dust exposure between 0.124 and 8.703 mg m(-3) for a sampling time of 2h. A field test was also carried out in a small factory where teak was used. A good correlation was confirmed between LP and DLP versus the dust collected on the filter in both cases.
3.A naphthoquinone derivative from Tectona grandis (Linn.).
Gupta PK;Singh P J Asian Nat Prod Res. 2004 Sep;6(3):237-40.
A new naphthoquinone derivative has been isolated, along with a number of prenylnaphthoquinone congeners, from the heartwood of Tectona grandis (Linn.). It was characterized as dehydro-alpha-isodunnione (1) by careful analysis of its spectral data.
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CAS 3568-90-9 Deoxylapachol

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