D-[2-13C]ribulose - CAS 131771-71-6
Molecular Formula:
13CC4H10O5
Molecular Weight:
151.12
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Tag:
13C-labelled Carbohydrates
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Synonyms:
D-[2-13C]erythro-pent-2-ulose
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1.5-Fluoro derivatives of 4-epi-isofagomine as d-galactosidase inhibitors and potential pharmacological chaperones for GM1-gangliosidosis as well as Fabry's disease.
Thonhofer M1, Gonzalez Santana A2, Fischer R3, Torvisco Gomez A3, Saf R4, Schalli M1, Stütz AE5, Withers SG2. Carbohydr Res. 2016 Feb;420:6-12. doi: 10.1016/j.carres.2015.10.009. Epub 2015 Dec 8.
Electrophilic fluorination of an exocyclic methoxymethylene enol ether derived from N-tert-butyloxycarbonyl-1,5-dideoxy-1,5-imino-3,4-O-isopropylidene-d-erythro-pent-2-ulose (11) provided the 5-fluoro derivative of the powerful β-galactosidase inhibitor 4-epi-isofagomine (8). This structural alteration, in combination with N-alkylation, led to considerably improved α-galactosidase selectivity. New compounds may serve as leads en route to new pharmacological chaperones for Fabry's disease.
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CAS 131771-71-6 D-[2-13C]ribulose

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