Bonducellpin D - CAS 197781-85-4
Catalog number: 197781-85-4
Not Intended for Therapeutic Use. For research use only.
Molecular Formula:
C22H28O7
Molecular Weight:
404.45
COA:
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Chemical Family:
Diterpenoids
Description:
Bonducellpin D is a natural diterpenoid compound found in several plants.
Purity:
>95%
Appearance:
Powder
Synonyms:
(3bS,3b1R,5aR,6S,6aR,10S,10aS,10bS)-6a,10-dihydroxy-7,7,10a-trimethyl-4-oxo-3b,3b1,5a,6,6a,7,8,9,10,10a,10b,11-dodecahydro-4H-phenanthro[3,2-b:10,1-b'c']difuran-6-yl acetate;(+)-Bonducellpin D
MSDS:
Inquire
Quality Standard:
Enterprise Standard
Quantity:
Milligrams-Grams
Density:
1.4±0.1 g/cm3
1.Caesalminaxins A-L, cassane diterpenoids from the seeds of Caesalpinia minax.
Zheng Y;Zhang SW;Cong HJ;Huang YJ;Xuan LJ J Nat Prod. 2013 Dec 27;76(12):2210-8. doi: 10.1021/np400545v. Epub 2013 Dec 4.
Fourteen new cassane diterpenoids, caesalminaxins A-L (1-14), and three known compounds were isolated from the seeds of Caesalpinia minax. Among the new diterpenoids, compounds 3 and 4 possess a rare spiro C/D ring system. The C-16 epimeric mixture 1/2 has an unprecedented carbon skeleton, presumably derived from 3 by cleavage of the C-13-C-14 bond. Compound 5 is the first example of a cassane diterpenoid with a spiro A/B ring system. The structures of the compounds were elucidated on the basis of 1D and 2D NMR analysis, and the absolute configurations of 3, 4, 9, and 11 were determined by single-crystal X-ray crystallography. Biosynthesis pathways for 1/2, 3, and 5 are postulated. Compounds 4, 8, and the known bonducellpin D exhibited moderate activity against four tested human cancer cell lines, HepG-2, K562, HeLa, and Du145.
2.Molecular structures and antiviral activities of naturally occurring and modified cassane furanoditerpenoids and friedelane triterpenoids from Caesalpinia minax.
Jiang RW;Ma SC;He ZD;Huang XS;But PP;Wang H;Chan SP;Ooi VE;Xu HX;Mak TC Bioorg Med Chem. 2002 Jul;10(7):2161-70.
Further investigation of the active components of the chloroform fraction of the seeds of Caesalpinia minax led to the isolation of a new cassane furanoditerpenoid, caesalmin H (1), together with two known furanoditerpenoid lactones, caesalmin B (2) and bonducellpin D (3). Reduction of the naturally abundant caesalmin D (9), E (10) and F (11) resulted in three new furanoditerpenoid derivatives 4-6. Phytochemical study of the stem of the same plant and subsequent reduction afforded two friedelane triterpenoids (7-8), which were identified by spectroscopic methods. Compounds 1-2 and 4-8 were corroborated by single crystal X-ray analysis. The factors governing the reduction of cassane furanoditerpenoids and friedelane triterpenoids were investigated by correlating the crystallographic results with density functional theory. The inhibitory activities of 2-8 on the Para3 virus were evaluated by cytopathogenic effects (CPE) reduction assay.
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