Allitol - CAS 488-44-8
Catalog number: 488-44-8
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Allitol isolated from the herb of Itea yunnanensis Franch. It is an important intermediate of some medicines against diabetes, cancer, and viral infections, including AIDS.
> 95%
Allitol is a sweetener and the raw material for chemical compounds, and it is a substrate for L-form ketoses and aldoses.
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1.Carbohydrate chelation in neutral aqueous solution: the threo-tetritolato-Pd(4) butterfly motif.
Allscher T1, Klüfers P. Chemistry. 2012 Aug 20;18(34):10571-84. doi: 10.1002/chem.201100979. Epub 2012 Jul 11.
Alditols ("sugar alcohols", "glycitols") form palladium(II) complexes in neutral aqueous solution if they can provide the threitol partial structure. This requirement excludes erythritol, ribitol, and allitol when applied to the common tetritols, pentitols, and hexitols. The remaining alditols are able to arrange their threo-tetraol-O(4) pattern to an almost planar rhomb, to which four Pd(II) N(2) (N(2) =bidentate nitrogen ligand) centres bind in a butterfly-shaped Pd(4) motif. Bridging is the exclusive bonding mode of the four alkoxido donors. In contrast to the butterfly complexes, all alditols are able to form a species at a pH intermediate between neutrality and the stronger alkaline conditions of non-bridging diolato-palladium(II) binding, namely, the μ-triolato bonding mode. A Pd(2) (μ-triolato) unit shows the middle O atom of a propanetriolato fragment as a bridging ligator, with the lateral O atoms binding in the terminal mode.
2.Cloning and characterization of a new ribitol dehydrogenase from Providencia alcalifaciens RIMD 1656011.
Hassanin HA1, Wang X1, Zhang T1, Mu W1, Jiang B1. J Sci Food Agric. 2015 Dec 23. doi: 10.1002/jsfa.7589. [Epub ahead of print]
BACKGROUND: A new ribitol dehydrogenase gene was cloned from Providencia alcalifaciens RIMD 1656011 and expressed in Escherichia coli BL21. This study aimed to purify and characterize the ribitol dehydrogenase from Providencia alcalifaciens RIMD 1656011 and study the substrate specificity for potential use as industrial enzyme.
3.[Chemical constituents of fresh celery].
Zhou K1, Wu B, Zhuang Y, Ding L, Liu Z, Qiu F. Zhongguo Zhong Yao Za Zhi. 2009 Jun;34(12):1512-5.
OBJECTIVE: To study the chemical constituents of the whole plant of fresh celery (Apium graveolens).
4.[Study on chemical constituents from stem of Dendrobium aphyllum].
Shao L1, Huang WH, Zhang CF, Wang L, Zhang M, Wang ZT. Zhongguo Zhong Yao Za Zhi. 2008 Jul;33(14):1693-5.
OBJECTIVE: To study the active constituents of Dendrobium aphyllum.
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CAS 488-44-8 Allitol

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