1,1-Ferrocenedimethanol - CAS 1291-48-1
Catalog number: 1291-48-1
Category: Main Product
Molecular Formula:
C12H14FeO2
Molecular Weight:
246.08
COA:
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Purity:
95%
Synonyms:
1,1-Ferrocenylbis(methanol), Cyclopentadienemethanol
MSDS:
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Quantity:
Data not available, please inquire.
Melting Point:
106-108ºC(lit.)
InChIKey:
ZFFYTNSKVXIYIE-UHFFFAOYSA-N
InChI:
InChI=1S/2C6H7O.Fe/c2*7-5-6-3-1-2-4-6;/h2*1-4,7H,5H2;
Canonical SMILES:
[CH]1[CH][CH][C]([CH]1)CO.[CH]1[CH][CH][C]([CH]1)CO.[Fe]
1.Electrochemically mediated reduction of horseradish peroxidase by 1,1'-ferrocenedimethanol in organic solvents.
Konash A1, Magner E. Anal Chem. 2005 Mar 15;77(6):1647-54.
Cyclic voltammetry is an efficient means of analyzing the catalytic reduction of H2O2 at immobilized horseradish peroxidase (HRP)-Eastman AQ 55 electrodes in the presence of 1,1'-ferrocenedimethanol as a one-electron reversible cosubstrate. This system was employed to study the kinetics of the reduction of compound II of HRP in a number of organic solvents. An electrocatalytic response was detected in methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, acetone, 2-butanone, 1,2-propanediol, acetonitrile, ethyl acetate, and ethylene glycol. Unusual bell-shaped variations of the peak or plateau catalytic current with the substrate concentration were observed in all solvents tested. The results obtained in methanol, acetonitrile, and 1-propanol were analyzed using the model developed by Saveant (Limoges, B.; Saveant, J.-M.; Yazidi, D. J. Am. Chem. Soc. 2003, 125, 9192-9203). The values of k3Gamma0 and K3,M, where k3 = k3,1k3,2/(k3,-1 + k3,2), Gamma0 is the surface concentration of active enzyme, and K3,M = (k3,-1 + k3,2)/k3,1, were determined.
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CAS 1291-48-1 1,1-Ferrocenedimethanol

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