trans-2-HEXEN-1-OL FCC - CAS 928-95-0
Category:
Flavor & Fragrance
Product Name:
trans-2-HEXEN-1-OL FCC
Synonyms:
(* Alt. CAS #) CAS: 2305-21-7; 2-Hexen-1-ol, 2-Hexen-1-ol, (2E)-, e-2-Hexenol, FEMA CAS: 2305-21-7, T-2-HEXEN-1-OL, T-2-HEXENOL, trans-2-HEXEN-1-OL FCC
CAS Number:
928-95-0
Molecular Weight:
100.16
Molecular Formula:
C6H12O
COA:
Inquire
MSDS:
Inquire
Olfactive Family:
Fruity | Green
FEMA:
2562
Odor description:
Sharp, green, leafy, fruity, unripe banana odor.
Taste description:
Sweet, fruity, slightly green, and fatty.
Chemical Structure
CAS 928-95-0 trans-2-HEXEN-1-OL FCC

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Reference Reading


1.Integration of olfactory information in the Colorado potato beetle brain.
De Jong R1, Visser JH. Brain Res. 1988 Apr 26;447(1):10-7.
The processing of olfactory information in the Colorado potato beetle, Leptinotarsa decemlineata Say, was studied by recording responses of olfactory neurones intracellularly in the deutocerebrum. Response characteristics of neurones in this first relay station of the olfactory pathway were measured when the antennae were stimulated with five general green leaf volatiles, i.e. cis-3-hexen-1-ol, trans-2-hexenal, cis-3-hexenyl acetate, trans-2-hexen-1-ol and 1-hexanol. These compounds are part of the so-called green odour of potato, whose defined composition is essential for the beetle's host plant finding. The response spectra of deutocerebral neurones can be divided roughly into two classes: one class containing neurones which are not very specific for the tested compounds, and another class with highly specialized neurones. Their different responses to a potato leaf extract suggest two channels for the processing of olfactory information in the antennal lobe: one channel for the detection of the presence of green leaf odour components, and another one for an evaluation of the component ratios.
2.Silica-Supported Tantalum Catalysts for Asymmetric Epoxidations of Allyl Alcohols.
Meunier D1, Piechaczyk A, de Mallmann A, Basset JM. Angew Chem Int Ed Engl. 1999 Dec 3;38(23):3540-3542.
Tantalum good, titanium bad: This appears to be the case for silica-supported catalysts for the asymmetric epoxidation of allyl alcohols. Complexes such as [SiO-Ta(OEt)(4)] were prepared from silica and [Ta(=CHCMe(3))(CH(2)CMe(3))(3)], and in the presence of a tartrate and an alkyl hydroperoxide, these surface tantalum compounds lead to efficient and convenient catalysts for the asymmetric epoxidation of 2-propen-1-ol (R=H) and trans-2-hexen-1-ol (R=nPr; see reaction).
3.Behavioral and electrophysiological responses of Aedes albopictus to certain acids and alcohols present in human skin emanations.
Guha L1, Seenivasagan T, Iqbal ST, Agrawal OP, Parashar BD. Parasitol Res. 2014 Oct;113(10):3781-7. doi: 10.1007/s00436-014-4044-0. Epub 2014 Jul 23.
Human skin emanations attract hungry female mosquitoes toward their host for blood feeding. In this study, we report the flight orientation and electroantennogram response of Aedes albopictus females to certain unsaturated acids and alcohols found in human skin. In the Y-tube olfactometer, odors of lactic acid and 2-methyl-3-pentanol attracted 54-65% of Ae. albopictus females at all doses in a dose-dependent manner. However, at the highest dose (10(-2) g), the acids repelled 40-45% females. Attractancy (ca. 62-68%) at lower doses and repellency (ca. 30-45%) at higher doses were recorded for 3-methyl-3-pentanol and 1-octen-3-ol, while 5-hexen-1-ol, cis-2-hexen-1-ol, and trans 2-hexen-1-ol odor repelled ca. 55-65% of Ae. albopictus females at all doses. Antenna of female Ae. albopictus exhibited a dose-dependent EAG response up to 10(-3) g of L-lactic acid, trans-2-methyl-2-pentenoic acid, 2-octenoic acid, trans-2-hexen-1-ol and 1-octen-3-ol stimulations; however, the highest dose (10(-2) g) caused a little decline in the EAG response.
4.Specificity-related suppression of responses to binary mixtures in olfactory receptors of the Colorado potato beetle.
De Jong R1, Visser JH. Brain Res. 1988 Apr 26;447(1):18-24.
Responses of antennal olfactory receptors of the Colorado potato beetle (Leptinotarsa decemlineata Say) to stimulation with 5 general green odour components, i.e. cis-3-hexen-1-ol, trans-2-hexenal, cis-3-hexenyl acetate, trans-2-hexen-1-ol and 1-hexanol, were recorded extracellularly. Response spectra derived from these recordings cannot be classified into distinct reaction types. The spectra overlap in their sensitivity to individual stimuli, but there are differences in their degree of specialization with a gradual conversion from generalist to specialist receptors. Moreover, specialization is found to different stimuli. Receptor reactions to stimulation with binary mixtures of 3 of these compounds indicated that suppression of the response to one chemical by another is very common in olfactory receptor cells. The more a receptor is specialized, the stronger is this suppression. Suppression in narrowly tuned olfactory receptor neurones, therefore, is expected to play a fundamental role in the recognition of natural odour blends.