(R)-(-)Massoialactone - CAS 51154-96-2
Catalog number: 51154-96-2
Category: Main Product
Molecular Formula:
C10H16O2
Molecular Weight:
168.23284
COA:
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Purity:
95%
Synonyms:
(R)-2-decen-5-olide; 2H-Pyran-2-one, 5,6-dihydro-6-pentyl-, (6R)-; (6R)-6-Pentyl-5,6-dihydro-2H-pyran-2-one; (6R)-6β-Pentyl-5,6-dihydro-2H-pyran-2-one; (R)-5,6-Dihydro-6-pentyl-2H-pyran-2-one; Massoilactone
MSDS:
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Boiling Point:
287ºC at 760mmHg
Density:
0.964g/cm3
InChIKey:
NEDIAPMWNCQWNW-SECBINFHSA-N
InChI:
InChI=1S/C10H16O2/c1-2-3-4-6-9-7-5-8-10(11)12-9/h5,8-9H,2-4,6-7H2,1H3/t9-/m1/s1
Canonical SMILES:
CCCCCC1CC=CC(=O)O1
1.Modular synthesis of optically active lactones by Ru-catalyzed asymmetric allylic carboxylation and ring-closing metathesis reaction.
Takii K1, Kanbayashi N, Onitsuka K. Chem Commun (Camb). 2012 Apr 21;48(32):3872-4. doi: 10.1039/c2cc18137a. Epub 2012 Mar 14.
A new synthetic route to optically active unsaturated γ- and δ-lactones has been demonstrated via asymmetric allylic carboxylation with a planar-chiral Cp'Ru catalyst and ring-closing metathesis reaction with a Grubbs II catalyst, and successfully applied to the enantioselective synthesis of (R)-(-)-massoialactone.
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CAS 51154-96-2 (R)-(-)Massoialactone

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