Ocimene quintoxide - CAS 7416-35-5
Catalog number: 7416-35-5
Category: Main Product
Molecular Formula:
C10H18O
Molecular Weight:
154.25
COA:
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Purity:
95%
Synonyms:
(± )-2,2-Dimethyl-5-(1-methyl-1-propenyl)tetrahydrofuran
MSDS:
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Boiling Point:
181.8ºC at 760 mmHg
Density:
0.865 g/mL at 25ºC(lit.)
1.Regio- and Stereochemical Control in Ocimene Polymerization by Half-Sandwich Rare-Earth Metal Dialkyl Complexes.
Peng D1, Du G1, Zhang P1, Yao B1, Li X1, Zhang S1. Macromol Rapid Commun. 2016 May 6. doi: 10.1002/marc.201600102. [Epub ahead of print]
The polymerization of ocimene has been first achieved by half-sandwich rare-earth metal dialkyl complexes in combination with activator and Ali Bu3 . The regio- and stereoselectivity in the ocimene polymerization can be controlled by tuning the cyclopentadienyl ligand and the central metal of the complex. The chiral cyclopentadienyl-ligated Sc complex 1 prepares syndiotactic cis-1,4-polyocimene (cis-1,4-selectivity up to 100%, rrrr = 100%), while the corresponding Lu, Y, and Dy complexes 2-4 and the achiral pentamethylcyclopentadienyl Sc, Lu, and Y complexes 5-7 afford isotactic trans-1,2-polyocimenes (trans-1,2-selectivity up to 100%, mm = 100%).
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CAS 7416-35-5 Ocimene quintoxide

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