METHYL ANISATE - CAS 121-98-2
Category:
Flavor & Fragrance
Product Name:
METHYL ANISATE
Synonyms:
Benzoic acid, 4-methoxy-, methyl ester, Methyl 4-methoxybenzoate, METHYL ANISATE, Methyl p-anisate
CAS Number:
121-98-2
Molecular Weight:
166.18
Molecular Formula:
C9H10O3
COA:
Inquire
MSDS:
Inquire
Olfactive Family:
Fruity
Odor description:
fruity
Chemical Structure
CAS 121-98-2 METHYL ANISATE

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Reference Reading


1.High-performance liquid chromatographic determinaton of pentaerythritol in plasma.
Bighley LD, Wurster DE, Cruden-Loeb C, Smith RV. J Chromatogr. 1975 Jul 16;110(2):375-80.
A sensitive analysis of pentaerythritol in plasma has been devised, based on the formation of its tetra-p-methoxybenzoate derivative and high-performance liquid chromatography employing an ultraviolet photometric detector. The method permits analysis of pentaerythritol in the ppm range.
2.Synthesis of a C(29)-C(51) subunit of spongistatin 1 (Altohyrtin A) starting from (R)-3-benzyloxy-2-methylpropan-1-ol.
Lemaire-Audoire S1, Vogel P. J Org Chem. 2000 Jun 2;65(11):3346-56.
A protected C(29)-C(51) subunit ((+)-38) of spongistatin 1 has been obtained. Key steps involve the aldol condensation of (3S, 4R)-3-methyl-7-[(p-methoxybenzyl)oxy]-4-[(triethylsilyl)oxy]octan- 2-o ne ((-)-6) with (tert-butyl)dimethylsilyl 4-deoxy-2, 3-di-O-(methoxymethyl)-4-methyl-6-O-(tert-butyl)dimethylsilyl)-bet a-D -glycero-L-gluco-heptodialdo-1,5-pyranoside ((+)-7) and a C-glycosidation of (4R,7R&S,E)-7, 8-dichloro-2-methylidene-1-(trimethylsilyl)oct-5-en-4-yl p-methoxybenzoate (16). Aldehyde (+)-7 was derived from (R)-3-benzyloxy-2-methylpropan-1-ol ((+)-10) in 13 formal steps but requiring the isolation of five intermediate products only. The longest linear synthetic scheme converts (+)-10 into (+)-38 in 2% overall yield (isolation of 11 intermediate products).
3.(2-Nitroethyl)benzene: a major flower scent from the Japanese loquat Eriobotrya japonica [Rosales: Rosaceae].
Kuwahara Y1, Ichiki Y, Morita M, Asano Y. Biosci Biotechnol Biochem. 2014;78(8):1320-3. doi: 10.1080/09168451.2014.921558. Epub 2014 Jun 12.
(2-Nitroethyl)benzene was identified as a major component of the flower scent of the Japanese loquat Eriobotrya japonica [Rosales: Rosaceae], together with p-methoxybenzaldehyde and methyl p-methoxybenzoate. The corresponding volatiles from chopped leaves did not contain these three compounds. This is the first time that 1-nitro-2-phenyl-ethane has been demonstrated to be a natural product among Japanese plants, although two Japanese millipedes are known to possess the same aromatics.