(+)-MENTHOXYACETIC ACID - CAS 94133-41-2
Category:
Main Product
Product Name:
(+)-MENTHOXYACETIC ACID
Catalog Number:
94133-41-2
Synonyms:
(+)-MENTHOXYACETIC ACID; (+)-MENTHYLOXYACETIC ACID; [1S-(1alpha,2beta,5alpha)]-[[5-methyl-2-(1-methylethyl)cyclohexyl]oxy]acetic acid; [[(1S)-2β-Isopropyl-5α-methylcyclohexane-1α-yl]oxy]acetic acid; [[(1S)-5α-Methyl-2β-(1-methylethyl)cyclohexan-1α-yl]oxy]ace
CAS Number:
94133-41-2
Molecular Weight:
214.3
Molecular Formula:
C12H22O3
COA:
Inquire
MSDS:
Inquire
Chemical Structure
CAS 94133-41-2 (+)-MENTHOXYACETIC ACID

Reference Reading


1.endo-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2-carboxylic acid, a superior resolving agent for the high-performance liquid chromatographic separation of enantiomers of hydroxylated derivatives of two azaaromatic hydrocarbons.
Duke CC1, Holder GM. J Chromatogr. 1988 Aug 19;430(1):53-64.
The high-performance liquid chromatographic (HPLC) separation of enantiomers of oxide and hydroxy derivatives of dibenz[a,j]acridine and 7-methylbenz[c]acridine was investigated on a chiral stationary phase chromatography column using commercially available columns. In most cases either poor or no separation of enantiomers was achieved. Normal-phase separation of diastereoisomeric ester derivatives of the hydroxy compounds, prepared from commercially available (-)-menthoxyacetic acid or (+)-alpha-methoxy-alpha-(trifluoromethyl)phenylacetic acid, was investigated. No separation of the diastereoisomeric esters of trans-3,4-dihydroxy-3,4-dihydrodibenz[a,j]acridine was observed. However, diastereoisomeric esters prepared from (+)-endo-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2-carboxyl ic acid [(+)-HCA] were easily separated. Using the three chiral acids, diastereoisomers were prepared from sixteen hydroxy derivatives of dibenz[a,j]acridine and 7-methylbenz[c]acridine.