(-)-ISOPINOCAMPHEYLAMINE - CAS 69460-11-3
Category:
Main Product
Product Name:
(-)-ISOPINOCAMPHEYLAMINE
Catalog Number:
69460-11-3
Synonyms:
(-)-ISOPINOCAMPHEYLAMINE; (1R,2R,3R,5S)-(-)-ISOPINOCAMPHEYLAMINE; (1R,2R,3R,5S)-3-PINANAMINE; (1R,2R,3R,5S)-(-)-ISOPINOCAMPHEYLAMINE,95%; (-)-Isopinocampheylamine, (1R,2R,3R,5S)-3-Pinanamine
CAS Number:
69460-11-3
Molecular Weight:
153.26
Molecular Formula:
C10H19N
COA:
Inquire
MSDS:
Inquire
Chemical Structure
CAS 69460-11-3 (-)-ISOPINOCAMPHEYLAMINE

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Reference Reading


1.Conformational change induced by hydration: trans-dichlorobis[(1R,2R,3R,5S)-(-)-isopinocampheylamine]palladium(II) and trans-dichlorobis[(1S,2S,3S,5R)-(+)-isopinocampheylamine]palladium(II) hemihydrate.
Vázquez J1, Bernès S, Meléndrez R, Portillo R, Gutiérrez R. Acta Crystallogr C. 2005 Sep;61(Pt 9):m424-7. Epub 2005 Aug 20.
The title compounds, trans-dichlorobis[(1R,2R,3R,5S)-(-)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine]palladium(II), [PdCl2(C10H19N)2], and trans-dichlorobis[(1S,2S,3S,5R)-(+)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine]palladium(II) hemihydrate, [PdCl2(C10H19N)2].0.5H2O, present different arrangements of the amine ligands coordinated to PdII, viz. antiperiplanar in the former case and (-)anticlinal in the latter. The hemihydrate is an inclusion compound, with a Pd coordination complex and disordered water molecules residing on crystallographic twofold axes. The crystal structure for the hemihydrate includes a short Pd...Pd separation of 3.4133 (13) A.