(-)-Corey lactone, 4-phenylbenzoate alcohol - CAS 31752-99-5
Category:
Main Product
Product Name:
(-)-Corey lactone, 4-phenylbenzoate alcohol
Catalog Number:
31752-99-5
Synonyms:
(3AALPHA,4ALPHA,5BETA,6AALPHA)-(-)-HEXAHYDRO-4-(HYDROXYMETHYL)-2-OXO-2H-CYCLOPENTA[B]FURAN-5-YL 1,1'-BIPHENYL-4-CARBOXYLATE; (-)-COREY LACTONE, 4-PHENYLBENZOATE ALCOHOL; (3aR,4S,5R,6aS)-Hexahydro-4-hydroxymethyl-5-(4-phenylbenzoyloxy)cyclopenta[b]furan-2-o
CAS Number:
31752-99-5
Molecular Weight:
352.39
Molecular Formula:
C21H20O5
COA:
Inquire
MSDS:
Inquire
Canonical SMILES:
C1C2C(CC(=O)O2)C(C1OC(=O)C3=CC=C(C=C3)C4=CC=CC=C4)CO
InChI:
InChI=1S/C21H20O5/c22-12-17-16-10-20(23)25-18(16)11-19(17)26-21(24)15-8-6-14(7-9-15)13-4-2-1-3-5-13/h1-9,16-19,22H,10-12H2/t16-,17-,18+,19-/m1/s1
InChIKey:
SZJVIFMPKWMGSX-AKHDSKFASA-N
Chemical Structure
CAS 31752-99-5 (-)-Corey lactone, 4-phenylbenzoate alcohol

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Reference Reading


1.An Improved and Efficient Process for the Preparation of (+)-cloprostenol.
Chen Y1, Yan H1, Chen HX1, Weng J1, Lu G1,2. Chirality. 2015 Jun;27(6):392-6. doi: 10.1002/chir.22457. Epub 2015 May 12.
An improved and efficient synthesis of (+)-cloprostenol has been accomplished in nine steps and 26% overall yield from commercially available (-)-Corey lactone 4-phenylbenzoate alcohol . The present route avoids tedious purifications and requires only one column chromatography operation, which reduces the generation of waste and is suitable for large-scale preparation.