cis-3-HEPTEN-1-OL - CAS 1708-81-2
Category:
Flavor & Fragrance
Product Name:
cis-3-HEPTEN-1-OL
Synonyms:
3-Hepten-1-ol, (3Z)-, cis-3-HEPTEN-1-OL, z-3-Heptenol
CAS Number:
1708-81-2
Molecular Weight:
114.19
Molecular Formula:
C7H14O
COA:
Inquire
MSDS:
Inquire
Olfactive Family:
Floral | Grass | Green
Odor description:
Green, freshly-mowed grass, herbaceous and floral odor.
Chemical Structure
CAS 1708-81-2 cis-3-HEPTEN-1-OL

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Reference Reading


1.Atmospheric Sink of (E)-3-Hexen-1-ol, (Z)-3-Hepten-1-ol, and (Z)-3-Octen-1-ol: Rate Coefficients and Mechanisms of the OH-Radical Initiated Degradation.
Gibilisco RG1, Blanco MB1, Bejan I2, Barnes I, Wiesen P, Teruel MA1. Environ Sci Technol. 2015 Jul 7;49(13):7717-25. doi: 10.1021/es506125c. Epub 2015 Jun 12.
A kinetic study of the gas-phase reactions of OH radicals with three unsaturated biogenic alcohols, (E)-3-hexen-1-ol, (Z)-3-hepten-1-ol, and (Z)-3-octen-1-ol, has been performed. The rate coefficients obtained are (in units of 10(-10) cm(3) molecule(-1) s(-1)) k1 (OH + (E)-CH2(OH)CH2CH═CHCH2CH3) = (1.14 ± 0.14), k2 (OH + (Z)-CH2(OH)CH2CH═CHCH2CH2CH3) = (1.28 ± 0.23), and k3 (OH + (Z)-CH2(OH)CH2CH═CHCH2CH2CH2CH3) = (1.49 ± 0.35). In addition, a product study on the reactions of OH with (E)-3-hexen-1-ol and (Z)-3-hepten-1-ol is reported. All the experiments were performed at (298 ± 2) K and 1 atm of NOx-free air in a 1080 L photoreactor with in situ FTIR detection of organics. This work constitutes the first kinetic study of the reactions of OH radicals with (Z)-3-hepten-1-ol and (Z)-3-octen-1-ol as well as the first determination of the fate of the hydroxy alkoxy radicals formed in the title reactions. An analysis of the available rates of addition of OH and Cl to the double bond of different unsaturated alcohols at 298 K has shown that they can be related by the expression log kOH = (0.