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(+)-CHLOROMETHYL ISOMENTHYL ETHER - CAS 26127-08-2

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Category
Main Product
Product Name
(+)-CHLOROMETHYL ISOMENTHYL ETHER
Catalog Number
26127-08-2
Synonyms
(+)-CHLOROMETHYL ISOMENTHYL ETHER; (-)-CHLOROMETHYL MENTHYL ETHER
CAS Number
26127-08-2
Molecular Weight
204.74
Molecular Formula
C11H21ClO
COA
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MSDS
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Structure
CAS 26127-08-2 (+)-CHLOROMETHYL ISOMENTHYL ETHER
Specification
Purity
95%
Boiling Point
249.1ºC at 760mmHg
Density
0.988 g/mL at 25 °C(lit.)
Reference Reading
1.Formylation of electron-rich aromatic rings mediated by dichloromethyl methyl ether and TiCl4: scope and limitations.
Ramos-Tomillero I1,2, Paradís-Bas M1,2, de Pinho Ribeiro Moreira I3,4, Bofill JM2,5, Nicolás E6,7, Albericio F8,9,10,11,12. Molecules. 2015 Mar 26;20(4):5409-22. doi: 10.3390/molecules20045409.
Here the aromatic formylation mediated by TiCl4 and dichloromethyl methyl ether previously described by our group has been explored for a wide range of aromatic rings, including phenols, methoxy- and methylbenzenes, as an excellent way to produce aromatic aldehydes. Here we determine that the regioselectivity of this process is highly promoted by the coordination between the atoms present in the aromatic moiety and those in the metal core.
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