Benzyl(methyl)sulfane - CAS 766-92-7
Catalog number: 766-92-7
Category: Main Product
Molecular Formula:
C8H10S
Molecular Weight:
138.23
COA:
Inquire
Purity:
98%
Appearance:
CLEAR COLOURLESS TO PALE YELLOW LIQUID
Synonyms:
SULFIDE, BENZYL METHYL; FEMA 3597; BENZYL METHYL SULFIDE; BENZYL METHYL SULPHIDE; (methylthiomethyl)benzene; [(Methylsulfanyl)methyl]benzene; [(methylthio)methyl]-benzen; 1-Phenyl-2-thiapropane
MSDS:
Inquire
Boiling Point:
195-198ºC
Melting Point:
-28ºC
Density:
1.01
Physical Description:
Benzyl methyl sulfide 98% (25g)
1.Excellent correlation between cathepsin B inhibition and cytotoxicity for a series of palladacycles.
Spencer J1, Casini A, Zava O, Rathnam RP, Velhanda SK, Pfeffer M, Callear SK, Hursthouse MB, Dyson PJ. Dalton Trans. 2009 Dec 28;(48):10731-5. doi: 10.1039/b912096c. Epub 2009 Aug 24.
The reaction of the five- or six-membered C,N or C,S-palladacycles [(L)PdCl](2) with PTA (1,3,5-triaza-7-phosphaadamantane) led to the monomeric complexes [(L)Pd(PTA)Cl] 6a, 6b and 7 where LH= N,N-dimethyl-1-phenylmethanamine, benzyl(methyl)sulfane or 1-methyl-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one respectively. Dimeric complexes have also been synthesised: [Pd(2)L(2)(mu-dppe)Cl(2)], where LH = 1-methyl-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one (1a), (R)- or (S)-3-isopropyl-1-methyl-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one (1b, 1c), [Pd(2)L(2)(mu-dppf)Cl(2)], where L= 1-methyl-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one (4a) or (R)-3-isopropyl-1-methyl-5-phenyl-1H-benzo[e][1,4]diazepin-2(3H)-one (4b), respectively, and dppe = 1,2-bis(diphenylphosphino)ethane, dppf = 1,1'-bis(diphenylphosphino)ferrocene. The complexes were characterised in solution, by (1)H and (31)P NMR spectroscopy, and single crystals of complexes 6b and 7 were studied in the solid state by X-ray crystallography.
Molecular Weight Calculator Molarity Calculator Solution Dilution Calculator

Related Products


Chemical Structure

CAS 766-92-7 Benzyl(methyl)sulfane

Quick Inquiry

Verification code

Featured Items