ANISALDEHYDE DIMETHYL ACETAL - CAS 2186-92-7
Category:
Flavor & Fragrance
Product Name:
ANISALDEHYDE DIMETHYL ACETAL
Synonyms:
ANISALDEHYDE DIMETHYL ACETAL, Anisaldehyde DMA, Benzene, 1-(dimethoxymethyl)-4-methoxy-, p-(Dimethoxymethyl)anisole
CAS Number:
2186-92-7
Molecular Weight:
182.22
Molecular Formula:
C10H14O3
COA:
Inquire
MSDS:
Inquire
Olfactive Family:
Floral
Odor description:
A mild, floral, hawthorn odor.
Chemical Structure
CAS 2186-92-7 ANISALDEHYDE DIMETHYL ACETAL

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Reference Reading


1.Synthetic mucin fragments. Benzyl O-(2-acetamido-2-deoxy-alpha-D-glucopyranosyl)-(1----3)-O-beta-D- galactopyranosyl-(1----3)-O-[(2-acetamido-2-deoxy-beta-D-glucopyran osy l)- (1----6)]-2-acetamido-2-deoxy-alpha-D-galactopyranoside and benzyl O-(2-acetamido-2-deoxy-beta-D-glucopyranosyl)-(1----3)-O-beta-D- galactopyranosyl-(1----3)-O-[beta-D-galactopyranosyl-(1----6)]-2-ac eta mido- 2-deoxy-alpha-D-galactopyranoside.
Thomas RL1, Abbas SA, Matta KL. Carbohydr Res. 1988 Dec 1;183(2):163-73.
Treatment of benzyl 2-acetamido-2-deoxy-alpha-D-galactopyranoside with 4-methoxybenzaldehyde dimethyl acetal in N,N-dimethylformamide in the presence of 4-toluenesulfonic acid afforded the 4,6-O-(4-methoxybenzylidene) acetal, which was glycosylated with 2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosyl bromide (1). Reductive ring-opening of the acetal group provided a 6-O-(4-methoxybenzyl) derivative (4) which was glycosylated with 1, followed by removal of the 4-methoxybenzyl ether group, to give benzyl 2-acetamido-2-deoxy-3,4-di-O-(2,3,4,6-tetra-O-acetyl-beta-D-galactopyran osyl)- alpha-D-galactopyranoside (7). The disaccharide diol 5, obtained from 4, and benzyl O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl-(1----3) -O- (2,4,6-tri-O-acetyl-beta-D-galactopyranosyl)-(1----3)-2-acetamido-2-deox y- alpha-D-galactopyranoside (11) were similarly glycosylated with 1 to afford a trisaccharide derivative 9 and a tetrasaccharide derivative 14, respectively.