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2-(3-HYDROXYPROP-1-YNYL)BENZONITRILE - CAS 210884-99-4

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Category
Main Product
Product Name
2-(3-HYDROXYPROP-1-YNYL)BENZONITRILE
Catalog Number
210884-99-4
Synonyms
2-(3-hydroxyprop-1-ynyl)benzonitrile;210884-99-4;2-(3-hydroxyprop-1-yn-1-yl)benzonitrile;ZINC02525642;AC1N4E1J;Ambcb4030363
CAS Number
210884-99-4
Molecular Weight
157.17
Molecular Formula
C10H7NO
COA
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MSDS
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Canonical SMILES
C1=CC=C(C(=C1)C#CCO)C#N
InChI
InChI=1S/C10H7NO/c11-8-10-5-2-1-4-9(10)6-3-7-12/h1-2,4-5,12H,7H2
InChIKey
ABSXJTJGIGJBOE-UHFFFAOYSA-N
Structure
CAS 210884-99-4 2-(3-HYDROXYPROP-1-YNYL)BENZONITRILE
Specification
Purity
95%
Boiling Point
341ºC at 760mmHg
Density
1.2g/cm3
Reference Reading
1.Synthesis of naphthalene amino esters and arylnaphthalene lactone lignans through tandem reactions of 2-alkynylbenzonitriles.
He Y1, Zhang X, Fan X. Chem Commun (Camb). 2014 May 30;50(42):5641-3. doi: 10.1039/c4cc01738b.
Tandem reaction of 2-alkynylbenzonitriles with a Reformatsky reagent turned out to be a novel and efficient approach toward 1-aminonaphthalene-2-carboxylates. Interestingly, with 2-(3-hydroxyprop-1-ynyl)benzonitriles as the substrates, a more sophisticated cascade process occurred to give 9-aminonaphtho[2,3-c]furan-1(3H)-ones in good yields. By using this tandem reaction as a key step, a concise and versatile synthetic strategy for the total synthesis of arylnaphthalene lactone lignans has been developed.
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