2,3,5-Tri-O-benzoyl-b-D-ribofuranosyl cyanide - CAS 23316-67-8
Category:
Carbohydrates
Product Name:
2,3,5-Tri-O-benzoyl-b-D-ribofuranosyl cyanide
CAS Number:
23316-67-8
Molecular Weight:
471.46
Molecular Formula:
C27H21NO7
COA:
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MSDS:
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Structure:
Monosaccharides
Chemical Structure
CAS 23316-67-8 2,3,5-Tri-O-benzoyl-b-D-ribofuranosyl cyanide

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Reference Reading


1.Synthesis of 1,2,4-triazole C-nucleosides from hydrazonyl chlorides and nitriles.
Al-Masoudi NA1, Al-Soud YA, Ali IA. Nucleosides Nucleotides Nucleic Acids. 2007;26(1):37-43.
A series of 1,3-diaryl-5-(2,3,5-tri-O-benzoyl-beta-D-ribofuranosyl)-1H-1,2,4-triazole nucleosides (3a-f) were synthesized via the intermolecular cyclization of hydrazonyl chlorides with peracylated ribofuranosyl cyanide catalyzed by Yb(OTf)3 or AgNO3, respectively. Similarly, the 1,2,4-triazole of glucopyranosyl C-nucleosides 5a,b were prepared from the hydrazonyl chlorides and the nitrile 4. Alternatively, the 1,2,4-triazole N-nucleoside 8 was obtained from cyclization of the unsymmetrical bis[alpha-(4-methoxyphenyl)aminobenzylidene]-hydrazine with peracylated 1-amino-D-manno-pentitol.