(1R)-CAMPHOR OXIME - CAS 2792-42-9
Category:
Main Product
Product Name:
(1R)-CAMPHOR OXIME
Catalog Number:
2792-42-9
Synonyms:
(+)-Camphor oxime; (2E)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one oxime; 1,7,7-trimethyl-,oxime,(1theta)-bicyclo[2.2.1]heptan-2-on; 2-Norbornyl oxime; bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,oxime,(1R)-; Camphor, oxime, (1R)-; camphor,oxime,(1R)-; D-CAMPHOR
CAS Number:
2792-42-9
Molecular Weight:
167.25
Molecular Formula:
C10H17NO
COA:
Inquire
MSDS:
Inquire
Chemical Structure
CAS 2792-42-9 (1R)-CAMPHOR OXIME

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Reference Reading


1.Evaluation of the acaricidal toxicities of camphor and its structural analogues against house dust mites by the impregnated fabric disc method.
Jeon JH1, Yang JY, Lee HS. Pest Manag Sci. 2014 Jul;70(7):1030-2. doi: 10.1002/ps.3769. Epub 2014 Mar 26.
BACKGROUND: The acaricidal activities of (±)-camphor structural analogues against house dust mites were evaluated using the impregnated fabric disc bioassay.
2.Asymmetric methoxyselenenylations and cyclizations with 3-camphorseleno electrophiles containing oxime substituents at C-2. Formation of an unusual oxaselenazole from an oxime-substituted selenenyl bromide.
Back TG1, Moussa Z, Parvez M. J Org Chem. 2002 Jan 25;67(2):499-509.
Di[(1R)-2-Oximo-endo-3-bornyl] diselenide (4) and its benzoate derivative 5 were prepared from the corresponding known 2-keto diselenide 1. Treatment of 4 and 5 with bromine, followed by silver triflate in methanol-dichloromethane, generated the corresponding selenenyl triflates 6b and 7b. The latter reagents reacted with a variety of mono-, di-, and trisubstituted alkenes to afford the corresponding 1,2-addition products (beta-methoxy selenides) in a highly diastereoselective manner. The free oxime 6b was particularly effective in such methoxyselenenylations, giving diastereomeric ratios (d.r.s) ranging from 86:14 to > 98:2. Even cis-disubstituted alkenes, which typically give poor d.r.s in similar additions with other chiral selenium electrophiles, underwent highly stereoselective additions with this reagent. Reductive deselenizations of the adducts obtained from styrene and cis- and trans-stilbene provided the corresponding methyl ethers, whose absolute configurations were determined by comparison with authentic samples.