1-Trimethylsilyl-1-pentyne - CAS 18270-17-2
Category:
Main Product
Product Name:
1-Trimethylsilyl-1-pentyne
Catalog Number:
18270-17-2
Synonyms:
1-PENTYN-1-YLTRIMETHYLSILANE; 1-(TRIMETHYLSILYL)-1-PENTYNE; TIMTEC-BB SBB009062
CAS Number:
18270-17-2
Molecular Weight:
140.30
Molecular Formula:
C8H16Si
COA:
Inquire
MSDS:
Inquire
Canonical SMILES:
CCCC#C[Si](C)(C)C
InChI:
InChI=1S/C8H16Si/c1-5-6-7-8-9(2,3)4/h5-6H2,1-4H3
InChIKey:
CABCDUQQPBAHEE-UHFFFAOYSA-N
Chemical Structure
CAS 18270-17-2 1-Trimethylsilyl-1-pentyne

Related Products


Reference Reading


1.Cobalt- versus ruthenium-catalyzed Alder-ene reaction for the synthesis of credneramide A and B.
Erver F1, Hilt G. J Org Chem. 2012 Jun 1;77(11):5215-9. doi: 10.1021/jo3007896. Epub 2012 May 11.
The first synthesis of the natural products credneramide A and B was accomplished by utilizing Alder-ene reactions between a terminal alkene and an internal alkyne to generate the rather uncommon 1,4-diene substructure of these compounds. Moreover, two different short linear sequences toward these targets are evaluated using either a cobalt-catalyzed Alder-ene reaction of 1-chloropent-1-yne or a ruthenium-catalyzed Alder-ene reaction of 1-trimethylsilyl-1-pentyne with 5-hexenoic acid derivatives in the key step transformation. In addition, saponification of the primary Alder-ene product derived from the cobalt-catalyzed Alder-ene reaction led to credneric acid, the biological precursor of both natural products.