(1-Phenyl-1H-1,2,3-triazol-4-yl)methanol - CAS 103755-58-4
Catalog number: 103755-58-4
Category: Main Product
Molecular Formula:
C9H9N3O
Molecular Weight:
175.19
COA:
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Purity:
95%
Synonyms:
(1-PHENYL-1H-1,2,3-TRIAZOL-4-YL)METHANOL; 1-Phenyl-1H-1,2,3-Triazol-4-yl
MSDS:
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Quantity:
Data not available, please inquire.
Boiling Point:
379.9ºC at 760 mmHg
Melting Point:
114-116ºC
Density:
1.27 g/cm3
InChIKey:
UBFOXHGJGFQOFV-UHFFFAOYSA-N
InChI:
InChI=1S/C9H9N3O/c13-7-8-6-12(11-10-8)9-4-2-1-3-5-9/h1-6,13H,7H2
Canonical SMILES:
C1=CC=C(C=C1)N2C=C(N=N2)CO
1.New tetradentate N,N,N,N-chelating α-diimine ligands and their corresponding zinc and nickel complexes: synthesis, characterisation and testing as olefin polymerisation catalysts.
Li L1, Gomes CS, Gomes PT, Duarte MT, Fan Z. Dalton Trans. 2011 Apr 7;40(13):3365-80. doi: 10.1039/c0dt01308k. Epub 2011 Feb 23.
A series of zinc complexes of the general formula {[ZnCl(ArN=C(An)-C(An)=NAr)](+)}(2)[Zn(2)Cl(6)](2-) (where Ar = 2-(1-benzyl-1H-1,2,3-triazol-4-yl)phenyl 2a, 2-(1-(1-phenylethyl)-1H-1,2,3-triazol-4-yl)phenyl 2b, 2-(1-phenyl-1H-1,2,3-triazol-4-yl)phenyl 2c; An = acenaphthene backbone) were prepared by the condensation of acenaphthenequinone with the corresponding o-triazolyl-substituted anilines (2-(1-benzyl-1H-1,2,3-triazol-4-yl)aniline 1a, 2-(1-(1-phenylethyl)-1H-1,2,3-triazol-4-yl)aniline 1b, 2-(1-phenyl-1H-1,2,3-triazol-4-yl)aniline 1c) which were formed by the copper(I)-catalyzed Huisgen[3+2] dipolar cycloaddition between 2-ethynylaniline and the corresponding azides in high yields, using anhydrous ZnCl(2) as the metal template, in boiling glacial acetic acid. Zinc complexes of the type [ZnCl(ArN=C(An)-C(An)=NAr)](+)[ZnCl(3)(NCCH(3))](-) (4a-c) were synthesized by crystallisation of the corresponding complexes 2a-c in acetonitrile, at -20 °C.
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CAS 103755-58-4 (1-Phenyl-1H-1,2,3-triazol-4-yl)methanol

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