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1,8-Dibenzyl-1,4,8,11-tetraazacyclotetradecane - CAS 214078-93-0

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Category
Main Product
Product Name
1,8-Dibenzyl-1,4,8,11-tetraazacyclotetradecane
Catalog Number
214078-93-0
Synonyms
1,8-dibenzyl-1,4,8,11-tetrazacyclotetradecane;1,8-DIBENZYL-1,4,8,11-TETRAAZACYCLOTETRADECANE;214078-93-0;ACMC-1CIDI;N(1),N(8)-Dibenzylcyclam;SCHEMBL10316935
CAS Number
214078-93-0
Molecular Weight
380.57
Molecular Formula
C24H36N4
COA
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MSDS
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Canonical SMILES
C1CNCCN(CCCNCCN(C1)CC2=CC=CC=C2)CC3=CC=CC=C3
InChI
InChI=1S/C24H36N4/c1-3-9-23(10-4-1)21-27-17-7-13-26-16-20-28(18-8-14-25-15-19-27)22-24-11-5-2-6-12-24/h1-6,9-12,25-26H,7-8,13-22H2
InChIKey
QWGFFCRTIFBAFJ-UHFFFAOYSA-N
Structure
CAS 214078-93-0 1,8-Dibenzyl-1,4,8,11-tetraazacyclotetradecane
Specification
Purity
95%
Boiling Point
514.1ºC at 760mmHg
Melting Point
67-68ºC
Density
1.003g/cm3
Reference Reading
1.Synthesis and structural studies of amido, hydrazido and imido zirconium(IV) complexes incorporating a diamido/diamine cyclam-based ligand.
Munhá RF1, Veiros LF, Duarte MT, Fryzuk MD, Martins AM. Dalton Trans. 2009 Sep 28;(36):7494-508. doi: 10.1039/b907335c. Epub 2009 Jul 24.
The preparation, characterisation and structural analysis of a series of zirconium(IV) complexes that incorporate the diamido/diamine macrocyclic ligand Bn2Cyclam (Bn2Cyclam = 1,8-dibenzyl-1,4,8,11-tetraazacyclotetradecane) are described. The reaction of one or two equivalents of the appropriate LiNHR reagents with [(Bn2Cyclam)ZrCl2] give the corresponding amido-chloride [(Bn2Cyclam)ZrCl(NHR)] (R = tBu, (2,6-iPr)Ph) or bis(amido) [(Bn2Cyclam)Zr(NHR)2] (R = iPr, tBu, (2,6-Me)Ph) complexes, respectively. Treatment of [(Bn2Cyclam)ZrCl(NH(2,6-iPr)Ph)] with one equiv. of MgClMe gives the base-free, monomeric imido complex [(Bn2Cyclam)Zr(N(2,6-iPr)Ph)]. The reaction of the tBu analog with MgClMe generates a dimeric bridging imido species [{(Bn2Cyclam)Zr}2(mu-NR)2], which can also be obtained by thermal decomposition of [(Bn2Cyclam)Zr(NHtBu)2] in toluene. The bis(hydrazido) complex [(Bn2Cyclam)Zr(NHNPh2)2] was obtained by reaction of [(Bn2Cyclam)ZrCl2] and two equiv.
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