1,5-Anhydro-4,6-O-benzylidene-D-glucitol - CAS 65190-39-8
Category:
Carbohydrates
Product Name:
1,5-Anhydro-4,6-O-benzylidene-D-glucitol
Synonyms:
2,6-Anhydro-1,3-O-benzylidenehexitol
CAS Number:
65190-39-8
Molecular Weight:
252.26
Molecular Formula:
C13H16O5
COA:
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MSDS:
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Structure:
Monosaccharides
Chemical Structure
CAS 65190-39-8 1,5-Anhydro-4,6-O-benzylidene-D-glucitol

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Reference Reading


1.A facile synthesis of 4,6-O-benzylidene-D-glycals via 1,5-anhydro-4,6-O-benzylidene-D-hex-1-en-3-ulose.
Sakakibara T1, Ito T, Kotaka C, Kajihara Y, Watanabe Y, Fujioka A. Carbohydr Res. 2008 Nov 3;343(16):2740-3. doi: 10.1016/j.carres.2008.05.018. Epub 2008 Jun 14.
Benzylidenation of readily available 1,5-anhydro-D-hex-1-en-3-ulose, followed by sodium borohydride reduction, afforded the title compounds in high yields. Separation of 4,6-O-benzylidene-D-allal and -D-glucal was accomplished by selective acetylation with lipase PS.