1,3,5,7-Tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane - CAS 27342-69-4
Catalog number: 27342-69-4
Category: Main Product
Molecular Formula:
C12H24O4Si4
Molecular Weight:
344.66
COA:
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Purity:
95%
Synonyms:
tetramethyltetravinylcyclotetrasiloxane; 1,3,5,7-Tetravinyl-1,3,5,7-Tetrmethylcyclotetrasiloxane; tetraethenyltetramethyl-cyclotetrasiloxan; 1,3,5,7-Tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane; 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane; Te
MSDS:
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Quantity:
Data not available, please inquire.
Boiling Point:
111-112ºC (10 mmHg)
Melting Point:
-44ºC
Density:
0.997
InChIKey:
VMAWODUEPLAHOE-UHFFFAOYSA-N
InChI:
InChI=1S/C12H24O4Si4/c1-9-17(5)13-18(6,10-2)15-20(8,12-4)16-19(7,11-3)14-17/h9-12H,1-4H2,5-8H3
Canonical SMILES:
C[Si]1(O[Si](O[Si](O[Si](O1)(C)C=C)(C)C=C)(C)C=C)C=C
1.Synthesis and applications of novel fluorinated dendrimer-type copolymers by the use of fluoroalkanoyl peroxide as a key intermediate.
Yoshioka H1, Suzuki M, Mugisawa M, Naitoh N, Sawada H. J Colloid Interface Sci. 2007 Apr 1;308(1):4-10. Epub 2006 Dec 16.
Fluoroalkanoyl peroxide reacted with 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane (TTRV-Si) to afford fluoroalkyl end-capped oligomers containing some unreacted vinyl segments under very mild conditions. Fluoroalkyl end-capped cyclosiloxane oligomers containing some vinyl segments thus obtained reacted with N,N-dimethylacrylamide and fluoroalkanoyl peroxide to afford new fluorinated dendrimer-type block copolymers in good isolated yield. Similar reactions were also occurred by the use of 1,3,5-trivinyl-1,3,5-trimethylcyclotrisiloxane instead of TTRV-Si, and the corresponding fluorinated dendrimer-type block copolymer was obtained in good isolated yield. These fluorinated dendrimer-type block copolymers had an excellent solubility not only in water but also in traditional organic solvents including aliphatic fluorinated solvents. Interestingly, these fluorinated block copolymers were found to form the self-assembled dendrimer-type polymeric aggregates in aqueous solutions.
2.Preceramic polysiloxane networks obtained by hydrosilylation of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane.
Nyczyk A1, Paluszkiewicz C, Pyda A, Hasik M. Spectrochim Acta A Mol Biomol Spectrosc. 2011 Aug 15;79(4):801-8. doi: 10.1016/j.saa.2010.08.056. Epub 2010 Sep 22.
Precreamic polysiloxane networks were prepared by hydrosilylation of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane (D(4)(Vi)) with a series of linear hydrogensiloxanes as well as with a cyclic hydrogensiloxane, namely 2,4,6,8-tetramethylcyclotetrasiloxane (D(4)(H)) at various hydrogensiloxane/D(4)(Vi) molar ratios in the starting reaction mixture. FTIR spectroscopic measurements conducted during the processes as well as for the reaction products allowed to reveal that the rate of D(4)(Vi) hydrosilylation as well as its efficiency are influenced by the type of hydrogensiloxane used and by the reactants molar ratio. Ceramic yields determined at 1000°C by thermogravimetric analyses were higher for D(4)(Vi)-D(4)(H) than for D(4)(Vi) - linear hydrogensiloxane networks (86-89% vs 65-76%, respectively). Preceramic polysiloxanes prepared as well as the products of their pyrolysis obtained after thermal investigations were monolithic, pore-less materials.
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CAS 27342-69-4 1,3,5,7-Tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane

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